If the dipoles of the polar binding reinforce each other, the molecule will be polar. If the shortcut dipoles cancel, the molecule will be nonpolar.

You are watching: A molecule which contains polar bonds will always have a dipole moment.

A molecule prefer H-F has two different atoms attached to each various other by a covalent bond.

The F atom has actually a greater tendency to lure the common electrons towards itself.

We say the it has a greater electronegativity.

It will have a partial negative charge, and also the H atom will have actually a partial confident charge.

We say that the bond is polar and has a dipole, since it has a partially hopeful “pole” and a partially negative “pole”.


We represent the dipole together an arrowhead with a ”plus” authorize at one end pointing in the direction a confident charge would certainly go — towards the an adverse end that the bond.

If a molecule has one polar bond, as in hydrogen fluoride, the centre of negative charge will certainly be in one place, and also the centre of an unfavorable charge will be in a different place.

The molecule as a whole will it is in polar.

If a molecule has much more than one polar bond, the molecule will certainly be polar or nonpolar, depending on how the bonds are arranged.

If the polar bonds are arranged symmetrically, the shortcut dipoles cancel and also do not create a molecule dipole.

For example, the three bonds in a molecule that BF₃ space polar, yet they suggest at angles of 120° about the main boron atom.

The center of hopeful charge is ~ above the boron atom, and the centre of the three an unfavorable charges is also on the boron atom.

Since the centres of positive and an adverse charges coincide, over there is no dipole moment, and also the molecule is nonpolar.


The O-H shortcut in a water molecule is polar, v its an adverse end in ~ the O atom and also its positive finish at the H atom.

The center of an adverse charge is ~ above the O atom, and the centre of optimistic charge is half-way between the 2 H atoms.

Since the centres of optimistic and an unfavorable charge perform not coincide, a water molecule is polar.

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There is great handout the the miscellaneous shapes of molecule that reflects which molecules are polar and also which room nonpolar despite having polar bonds.